Publications
Publications Articles / Book Chapters
68) Ion mobility studies of pyrroloquinoline quinone aza-crown ether lanthanide complexes
A. Schäfer, V. A. Vetsova, E. K. Schneider, M. Kappes, M. Seitz, L. J. Daumann,* Patrick Weis,* J. Am. Soc. Mass Spectrom. 2022, 33, ASAP. DOI: https://doi.org/10.1021/jasms.2c00023
67) Bright Luminescence by Combining Chiral [2.2]Paracyclophane with a Boron-Nitrogen-Doped Polyaromatic Hydrocarbon Building Block
M. R. Rapp, W. Leis, F. Zinna, L. Di Bari, T. Arnold, B. Speiser, M. Seitz, H. F. Bettinger,* Chem. Eur. J. 2022, 28, e202104161 DOI: https://doi.org/10.1002/chem.202104161
66) Strongly Red-Emissive Molecular Ruby [Cr(bpmp)2]3+ surpasses [Ru(bpy)3]2+
F. Reichenauer, C. Wang, C. Förster, P. Boden, N. Ugur, R. Baez-Cruz, J. Kalmbach, L. M. Carella, E. Rentschler, C. Ramanan, G. Niedner-Schatteburg, M. Gerhards, M. Seitz,*, U. Resch-Genger,* K. Heinze,* J. Am. Chem. Soc. 2021, 143, 11843. DOI: https://doi.org/10.1021/jacs.1c05971
65) Ultrafast and long-time excited state kinetics of an NIR-emissive vanadium(III) complex I: Synthesis, spectroscopy and static quantum chemistry
M. Dorn, J. Kalmbach, P. Boden, A. Kruse, C. Dab, C. Reber, G. Niedner-Schatteburg, S. Lochbrunner, M. Gerhards, M. Seitz,* K. Heinze,* Chem. Sci. 2021, 12, 10780. DOI: https://doi.org/10.1039/D1SC02137K
64) Distinct photodynamics of κ-N and κ-C pseudoisomeric iron(II) complexes
P. Dierks, A. Kruse, O. S. Bokareva, M. J. Al-Marri, J. Kalmbach, M. Baltrun, A. Neuba, R. Schoch, S. Hohloch, K. Heinze, M. Seitz, O. Kühn, S. Lochbrunner, M. Bauer,* Chem. Commun. 2021 57, 6640. DOI: https://doi.org/10.1039/D1CC01716K
63) Vacancy control in acene blends links exothermic singlet fission to coherence
C. Zeiser, C. Cruz, D. R. Reichman, M. Seitz, J. Hagenlocher, E. L. Chronister, C. Bardeen, R. Tempelaar, K. Broch,* Nat. Commun. 2021, 12, 5149. DOI: https://doi.org/10.1038/s41467-021-25395-9
62) Speracryptates - The Next Generation of Ultrastable Metal Complexes and the Discovery of Sodium/Proton Spheradicryptates
M. F. K. Trautnitz, T. Haas, W. Leis, P. Weis, L. Wesemann, M. M. Kappes, M. Seitz*, submitted.
61) Rare-earth coordination polymers with multimodal luminescenceon nano-, micro-, and milli-second time scales
M. Jacoby, C. Beil, P. Nazari, Bryce S. Richards, M. Seitz,* A. Turshatov,* I. A. Howard*, iScience 2021, 24, 102207. DOI: https://doi.org/10.1016/j.isci.2021.102207
60) Unexpected Discovery of Calcium Cryptates with Exceptional Stability
M. F. K. Trautnitz, T. Haas, H. Schubert, M. Seitz,* Chem. Comm. 2020, 56, 9874.
DOI: https://doi.org/10.1039/d0cc04050a
59) Near-IR to Near-IR Upconversion Luminescence in Molecular Chromium Ytterbium Salts
J. Kalmbach, C. Wang, Y. You, C. Förster, H. Schubert, K. Heinze,* U. Resch-Genger,* M. Seitz,* Angew. Chem. Int. Ed. 2020, 59, 18804 (Open Access). DOI: https://doi.org/10.1002/anie.202007200
58) Lanthanide Sensitizers for Large Anti-Stokes Shift NIR-to-VIS Triplet-Triplet Annihilation Photon Upconversion
N. Kiseleva, P. Nazari, C. Dee, D. Busko, B. S. Richards, M. Seitz, I. A. Howard,* A. Turshatov,* J. Phys. Chem. Lett. 2020, 11, 2477. DOI: https://doi.org/10.1021/acs.jpclett.0c00221
57) Modulating the electronic and solid state structures of organic semiconductors by site-specific Substitution: the case of tetrafluoropentacene T. Geiger, S. Schundelmeier, T. Hummel, M. Ströbele, W. Leis, M. Seitz, C. Zeiser, L. Moretti, M. Maiuri, G. Cerullo, K. Broch, J. Vahland, K. Leo, C. Maichle-Mössmer, B. Speiser, H. F. Bettinger,* Chem. Eur. J. 2020, 26, 3420 (Open Access).
DOI: https://doi.org/10.1002/chem.201905843
56) A vanadium(III) complex with blue and NIR-II spin-flip luminescence in solution
M. Dorn, J. Kalmbach, P. Boden, A. Päpcke, S. Gomez, C. Förster, F. Kuczelinis, L. M. Carella, L. Büldt, N. Bings, E. Rentschler, S. Lochbrunner, L. Gonzalez, M. Gerhards,* M. Seitz,* K. Heinze,* J. Am. Chem. Soc. 2020, 142, 7947. DOI: https://doi.org/10.1021/jacs.0c02122
55) Circularly Polarized Luminescence of Enantiopure Carboline-Based Europium Cryptates under Visible Light Excitation
C. Dee, F. Zinna, E. Kreidt, L. Arrico, A. Rodriguez-Rodriguez, C. Platas-Igleasias,* L. Di Bari,* M. Seitz,* J. Rare Earths 2020, 38, 564. DOI: https://doi.org/10.1016/j.jre.2020.01.014
54) Optical Materials - Molecules
M. Seitz, Rare Earth Chemistry (De Gruyter STEM series), Eds: R. Pöttgen, T. Jüstel, C. A. Strassert, De Gruyter, Berlin. ISBN-13: 978-31100653601
53) Direct Solid-Phase Synthesis of Molecular, Heterooligonuclear Lanthanoid-Complexes
E. Kreidt, W. Leis, M. Seitz,* Nat. Commun. 2020, 11, 1346. DOI: https://doi.org/10.1038/s41467-020-15199-8 Additional blog post here. (featured also in: Trendberichte Anorganische Chemie "Nachrichten aus der Chemie 2021, Januar") 52) Strong Circularly Polarized Luminescence of an Octahedral Chromium(III) Complex
C. Dee, F. Zinna, W. R. Kitzmann, G. Pescitelli, K. Heinze,* L. Di Bari,* M. Seitz,* Chem. Comm. 2019, 55, 13078. DOI: http://dx.doi.org/10.1039/c9cc06909g
51) Luminescence and Light-driven Energy and Electron Transfer from an Exceptionally Long-lived Excited State of a Non-innocent Chromium Complex
S. Treiling, C. Wang, C. Förster, F. Reichenauer, J. Kalmbach, P. Boden, J. P. Harris, L. Carrella, E. Rentschler, U. Resch-Genger, C. Reber, M. Seitz, M. Gerhards, K. Heinze,* Angew. Chem. Int. Ed. 2019, 58, 18075. DOI: http://dx.doi.org/10.1002/anie.201909325
50) Radiative Lifetime, Non-Radiative Relaxation, and Sensitization Efficiency in Luminescent Europium and Neodymium Cryptates - The Roles of 2,2'-Bipyridine-N,N'-Dioxide and Deuteration
M. F. K. Trautnitz, C. Doffek, M. Seitz,* ChemPhysChem 2019, 20, 2179. DOI: http://dx.doi.org/10.1002/cphc.201900673
49) Efficient Ytterbium Near-Infrared Luminophore Based on a Nondeuterated Ligand C. Kruck, P. Nazari, C. Dee, B. S. Richards, A. Turshatov,* M. Seitz,* Inorg. Chem. 2019, 58, 6959. DOI: http://dx.doi.org/10.1021/acs.inorgchem.9b00548 48) Understanding the Optical and Magnetic Properties of Ytterbium(III) Complexes D. Esteban-Gomez, L. A. Büldt, P. Perez-Lourido, L. Valencia, M. Seitz,* C. Platas-Iglesias,* Inorg. Chem. 2019, 58, 3732. DOI: http://dx.doi.org/10.1021/acs.inorgchem.8b03354
47) Circularly Polarised Luminescence in Enantiopure Samarium and Europium Cryptates E. Kreidt, L. Arrico, F. Zinna, L. Di Bari,* M. Seitz,* Chem. Eur. J. 2018, 24, 13556. DOI: http://dx.doi.org/10.1002/chem.201802196
46) Long-Wavelength Excitation of Europium Luminescence in Extended, Carboline-Based Cryptates C. Dee, D. Esteban-Gomez, C. Platas-Iglesias,* M. Seitz,* Inorg. Chem. 2018, 57, 7390. DOI: http://dx.doi.org/10.1021/acs.inorgchem.8b01031
45) Non-radiative Deactivation of Lanthanoid Luminescence by Multiphonon Relaxation in Molecular Complexes E. Kreidt, C. Kruck, M. Seitz, Handbook on the Physics and Chemistry of Rare Earths (Vol. 53), Elsevier, Amsterdam, 2018, 35. DOI: https://doi.org/10.1016/bs.hpcre.2018.04.001 44) Understanding and Exploiting Long-Lived Near-Infrared Emission of Molecular Ruby S. Otto, M. Dorn, C. Förster, M. Bauer, M. Seitz, K. Heinze, Coord. Chem. Rev. 2018, 359, 102. DOI: http://dx.doi.org/10.1016/j.ccr.2018.01.004 43) Anion dependent ion pairing in concentrated ytterbium halide solution C. Klinkhammer, F. Böhm, V. Sharma, M. Seitz, G. Schwaab, M. Havenith, J. Chem. Phys. 2018, 148, 222802. DOI:http://dx.doi.org/10.1063/1.5016549
42) Deuterated Molecular Ruby With Record Luminescence Quantum Yield C. Wang, S. Otto, M. Dorn, E. Kreidt, J. Lebon, L. Srsan, P. Di Martino-Fumo, M. Gerhards, U. Resch-Genger, M. Seitz, K. Heinze, Angew. Chem. Int. Ed. 2018, 57, 1112. DOI: http://dx.doi.org/10.1002/anie.201711350
41) Chiral Resolution of Lanthanoid Cryptates with Extreme Configurational Stability E. Kreidt, C. Dee, M. Seitz, Inorg. Chem. 2017, 56, 8752. DOI: http://dx.doi.org/10.1021/acs.inorgchem.7b01407 40) Extending the Excitation Wavelength of Potential Photosensitizers via Appendage of Kinetically-Stable Terbium(III) Macrocyclic Complex for Application in Photodynamic Therapy P. Ung, M. Clerc, H. Huang, K. Qiu, H. Chao, M. Seitz, B. Boyd, B. Graham, G. Gasser, Inorg. Chem. 2017, 56, 7960. DOI: http://dx.doi.org/10.1021/acs.inorgchem.7b00677
39) Magnetic Anisotropy in Functionalized Bipyridyl Cryptates E. Kreidt, C. Bischof, C. Platas-Iglesias, M. Seitz, Inorg. Chem. 2016, 55, 5549. DOI: http://dx.doi.org/10.1021/acs.inorgchem.6b00591 Correction/Addition: DOI: http://dx.doi.org/10.1021/acs.inorgchem.6b01367
38) Non-Radiative Deactivation of Lanthanoid Excited States by Inner-Sphere Carboxylates J. Wahsner, M. Seitz, Inorg. Chem. 2015, 54, 10841-10848. DOI: http://dx.doi.org/10.1021/acs.inorgchem.5b01920 37) Synthesis of Inert Homo- and Heterodinuclear Rare Earth Cryptates J. Wahsner, M. Seitz, Inorg. Chem. 2015, 54, 9681-9683. DOI: http://dx.doi.org/10.1021/acs.inorgchem.5b01922 36) The Radiative Lifetime in Near-IR-Luminescent Ytterbium Cryptates: The Key to Extremely High Quantum Yields C. Doffek, M. Seitz, Angew. Chem. Int. Ed. 2015, 54, 9719-9721. DOI: http://dx.doi.org/10.1002/anie.201502475
35) Breakdown of the Energy Gap Law in Molecular Lanthanoid Luminescence: The Smallest Energy Gap Is Not Universally Relevant for Nonradiative Deactivation C. Doffek, J. Wahsner, E. Kreidt, M. Seitz, Inorg. Chem. 2014, 53, 3263-3265. DOI: http://dx.doi.org/10.1021/ic500017a 34) Perdeuterated 2,2'-Bipyridine-6,6'-Dicarboxylate - An Extremely Efficient Sensitizer for Thulium Luminescence in Solution. J. Wahsner, M. Seitz, Inorg. Chem. 2013, 52, 13301-13303. DOI: http://dx.doi.org/10.1021/ic402652t
33) The First Enantiopure Lanthanoid Cryptate. T. Güden-Silber, C. Doffek, C. Platas-Iglesias, M. Seitz, Dalton Trans. 2014, 43, 4238-4241. (Invited contribution for the themed issue "New Talent: Europe"). DOI: http://dx.doi.org/10.1039/C3DT51289D
32) 4,4'-Bis(trifluoromethyl)-2,2'-Bipyridine - A Multipurpose Ligand Scaffold for Lanthanoid-Based Luminescence / 19F NMR Probes. T. Güden-Silber, K. Klein, M. Seitz, Dalton Trans. 2013, 42, 13882-13888. DOI: http://dx.doi.org/10.1039/C3DT50842K
31) From Solvated Ions to Ion-Pairing: A THz Study of Lanthanum(III) Hydration. V. Sharma, F. Böhm, M. Seitz, G. Schwaab, M. Havenith, Phys. Chem. Chem. Phys. 2013, 15, 8383-8391. DOI: http://dx.doi.org/10.1039/C3CP50865J
30) Understanding the Quenching Effects of Aromatic C-H- and C-D-Oscillators in Near-IR Lanthanoid Luminescence. C. Doffek, N. Alzakhem, C. Bischof, J. Wahsner, T. Güden-Silber, J. Lügger, C. Platas-Iglesias, M. Seitz, J. Am. Chem. Soc. 2012, 134, 16413-16423. DOI: http://dx.doi.org/10.1021/ja307339f 29) Anomalous Reversal of C-H and C-D Quenching Efficiencies in Luminescent Praseodymium Cryptates. J. Scholten, G.A. Rosser, J. Wahsner, N. Alzakhem, C. Bischof, F. Stog, A. Beeby, M. Seitz, J. Am. Chem. Soc. 2012, 134, 13915-13917. DOI: http://dx.doi.org/10.1021/ja306052u 28) Dependence of the Photophysical Properties on the Number of 2,2'-Bipyridine Units in a Series of Luminescent Europium and Terbium Cryptates. N. Alzakhem, C. Bischof, M. Seitz, Inorg. Chem. 2012, 51, 9343-9349. DOI: http://dx.doi.org/10.1021/ic3010568 27) Rigid, Perdeuterated Lanthanoid Cryptates - Extraordinarily Bright Near-IR Luminophores. C. Doffek, N. Alzakhem, M. Molon, M. Seitz, Inorg. Chem. 2012, 51, 4539-4545. DOI: http://dx.doi.org/10.1021/ic202376k
26) Synthesis, Characterisation and Bioimaging of a Fluorescent Rhenium-Containing PNA Bioconjugates. G. Gasser, A. Pinto, S. Neumann, A.M. Sosniak, M. Seitz, K. Merz, R. Heumann, N. Metzler-Nolte, Dalton Trans. 2012, 41, 2304-2313. DOI: http://dx.doi.org/10.1039/c2dt12114j
25) Preparation and Biological Evaluation of Di-Hetero Organometallic-Containing PNA Bioconjugates. G. Gasser, S. Neumann, I. Ott, M. Seitz, R. Heumann, N. Metzler-Nolte Eur. J. Inorg. Chem 2011, 5471-5478. DOI: http://dx.doi.org/10.1002/ejic.201100734
24) Quantification of C-H Quenching in Near-IR Luminescent Ytterbium and Neodymium Cryptates. C. Bischof, J. Wahsner, J. Scholten, S. Trosien, M. Seitz, J. Am. Chem. Soc. 2010, 132, 14334-14335. DOI: http://dx.doi.org/10.1021/ja105768w
23) 3,2-HOPO Complexes of Near Infra-Red (NIR) Emitting Lanthanides: Efficient Sensitization of Yb(III) and Nd(III) in Aqueous Solution. E.G. Moore, J. Xu, S.C. Dodani, C.J. Jocher, A. D'Aleo, M. Seitz, K.N. Raymond, Inorg. Chem. 2010, 49, 4156-4166. DOI: http://dx.doi.org/10.1021/ic902219t 22) Computational Estimation of Lanthanoid-Water Bond Lengths by Semiempirical Methods. M. Seitz, N. Alzakhem, J. Chem. Inf. Model. 2010, 50, 217-220. DOI: http://dx.doi.org/10.1021/ci9003442 21) Circularly Polarized Luminescence in Enantiopure Europium and Terbium Complexes with Modular, All-Oxygen Donor Ligands. M. Seitz, K. Do, A.J. Ingram, E.G. Moore, G. Muller, K.N. Raymond, Inorg. Chem. 2009, 48, 8469-8479. DOI: http://dx.doi.org/10.1021/ic901079s 20) Highly Fluorescent Group 13 Metal Complexes With Cyclic, Aromatic Hydroxamic Acid Ligands. M. Seitz, E.G. Moore, K.N. Raymond, Inorg. Chem. 2008, 47, 8665. DOI: http://dx.doi.org/10.1021/ic800269w 19) Use of YbIII-Centered Near-Infrared (NIR) Luminescence To Determine the Hydration State of a 3,2-HOPO-Based MRI Contrast Agent. E.G. Moore, M. Seitz, K.N. Raymond, Inorg. Chem. 2008, 47, 8571. DOI: http://dx.doi.org/10.1021/ic801060x 18) Efficient route to highly water-soluble aromatic cyclic hydroxamic acid ligands. M. Seitz, K.N. Raymond, Eur. J. Org. Chem. 2008, 2697. DOI: http://dx.doi.org/10.1002/ejoc.200800147 17) Enantiopure, Octadentate Ligands as Sensitizers for Europium and Terbium Circularly Polarized Luminescence in Aqueous Solution. M. Seitz, E.G. Moore, A.J. Ingram, G. Muller, K.N. Raymond, J. Am. Chem. Soc. 2007, 129, 15468. DOI: http://dx.doi.org/10.1021/ja076005e 16) The Lanthanide Contraction Revisited. M. Seitz, A.G. Oliver, K.N. Raymond, J. Am. Chem. Soc. 2007, 129, 11153. DOI: http://dx.doi.org/10.1021/ja072750f 15) 1,2-HOIQO - A Highly Versatile 1,2-HOPO Analogue. M. Seitz, M.D. Pluth, K.N. Raymond, Inorg. Chem. 2007, 46, 351. DOI: http://dx.doi.org/10.1021/ic0614869 14) Bis(pentamethylcyclopentadienyl)[(trimethylsilyl)methyl]scandium(III). S.G. Minasian, J.D. Rinehart, P. Bazinet, M. Seitz, Acta Crystallogr., Sect. E: Struct. Rep. Online 2006, 62, m1823. DOI: http://dx.doi.org/10.1107/S1600536806026602 13) Modular synthesis of chiral pentadentate bis(oxazoline) ligands. M. Seitz, A. Kaiser, A. Tereshchenko, C. Geiger, Y. Uematsu, O. Reiser, Tetrahedron 2006, 62, 9973. DOI: http://dx.doi.org/10.1016/j.tet.2006.08.003 12) (L)-[(R,R)-2,6-Bis(2-phenyl-4,5-dihydrooxazol-4-ylmethoxymethyl)pyridine]zinc(II) bis(trifluoromethane- sulfonate) dichloromethane solvate. M. Seitz, M. Zabel, O. Reiser, Acta Crystallogr., Sect. E: Struct. Rep. Online 2006, 62, m1517. DOI: http://dx.doi.org/10.1107/S1600536806021210 11) Synthetic approaches towards structurally diverse g-butyrolactone natural-product-like compounds. M. Seitz, O. Reiser, Curr. Opin. Chem. Biol. 2005, 9, 285. DOI: http://dx.doi.org/10.1016/j.cbpa.2005.03.005 10) Enantiomerically Pure Pentagonal-Bipyramidal Metal Complexes with Predetermined Helicity in the Solid and Solution States. M. Seitz, A. Kaiser, S. Stempfhuber, M. Zabel, O. Reiser, Inorg. Chem. 2005, 44, 4630. DOI: http://dx.doi.org/10.1021/ic050014b 9) Helical chirality in pentacoordinate zinc complexes - Selective access to both pseudoenantiomers with one ligand configuration. M. Seitz, S. Stempfhuber, M. Zabel, M. Schütz, O. Reiser, Angew. Chem. Int. Ed. 2005, 44, 242. DOI: http://dx.doi.org/10.1002/anie.200460843 8) Predetermined helical chirality in octahedral complexes with a novel pentadentate C2-symmetrical chiral bis(oxazoline) ligand. M. Seitz, A. Kaiser, D.R. Powell, A.S. Borovik, O. Reiser, Adv. Synth. Catal. 2004, 346, 737. DOI: http://dx.doi.org/10.1002/adsc.200404020 7) Helical, Nonracemic Inorganic-Organic Hybrid Polymers of Cadmium Halides with Pentadentate Bis(oxazoline) Ligands. M. Seitz, A. Kaiser, S. Stempfhuber, M. Zabel, O. Reiser, J. Am. Chem. Soc. 2004, 126, 11426. DOI: http://dx.doi.org/10.1021/ja0469784 6) New bis(oxazoline) ligands with secondary binding sites for the asymmetric cyclopropanation of furans. M. Schinnerl, C. Böhm, M. Seitz, O. Reiser, Tetrahedron: Asymmetry 2003, 14, 765. DOI: http://dx.doi.org/10.1016/S0957-4166(03)00094-6
5) Enantioselective synthesis of paraconic acids. R. B. Chhor, B. Nosse, S. Sörgel, C. Böhm, M. Seitz, O. Reiser, Chem. Eur. J. 2003, 9, 260. DOI: http://dx.doi.org/10.1002/chem.200390019 4) New Applications of Bis(oxazoline) Ligands in Catalysis: Asymmetric 1,2- and 1,4-Addition of ZnR2 to Carbonyl Compounds. M. Schinnerl, M. Seitz, A. Kaiser, O. Reiser, Org. Lett. 2001, 3, 4259. DOI: http://dx.doi.org/10.1021/ol016925g Patents / Book Reviews
3) Pentacoordinating bis(oxazoline) ligands with secondary binding sites (in: Activating Unreactive Substrates: The Role of Secondary Interactions; Eds.: C. Bolm, F.E. Hahn) C.A. Schall, M. Seitz, A. Kaiser, O. Reiser, Wiley-VCH, Weinheim 2009. ISBN: 9783527318230. 2) Preparation of 2-hydroxy-1-oxo-1,2-dihydroisoquinoline chelating agents and their lanthanide complexes with diagnostic and pharmaceutical applications. M. Seitz, K.N. Raymond, Patent WO2007/121453 (2007). 1) Principles and Applications of Asymmetric Synthesis (Book Review). M. Seitz, Angew. Chem. Int. Ed. 2001, 40, 3922. DOI: http://dx.doi.org/10.1002/1521-3773(20011015)40:20%3C3922::AID-ANIE3922%3E3.0.CO;2-P |