Publications

Articles

 

41) Chiral Resolution of Lanthanoid Cryptates with Extreme Configurational Stability

E. Kreidt, C. Dee, M. Seitz, submitted.


40) Extending the Excitation Wavelength of Potential Photosensitizers via Appendage of Kinetically-Stable

Terbium(III) Macrocyclic Complex for Application in Photodynamic Therapy

P. Ung, M. Clerc, H. Huang, K. Qiu, H. Chao, M. Seitz, B. Boyd, B. Graham, G. Gasser, Inorg. Chem. 2017, 56, accepted.

DOI: (tbd)

 

39) Magnetic Anisotropy in Functionalized Bipyridyl Cryptates

E. Kreidt, C. Bischof, C. Platas-Iglesias, M. Seitz, Inorg. Chem. 2016, 55, ASAP.

DOI: http://dx.doi.org/10.1021/acs.inorgchem.6b00591

Correction/Addition: DOI: http://dx.doi.org/10.1021/acs.inorgchem.6b01367

 

38) Non-Radiative Deactivation of Lanthanoid Excited States by Inner-Sphere Carboxylates

J. Wahsner, M. Seitz, Inorg. Chem. 2015, 54, 10841-10848.

DOI: http://dx.doi.org/10.1021/acs.inorgchem.5b01920


37) Synthesis of Inert Homo- and Heterodinuclear Rare Earth Cryptates

J. Wahsner, M. Seitz, Inorg. Chem. 2015, 54, 9681-9683.

DOI: http://dx.doi.org/10.1021/acs.inorgchem.5b01922


36) The Radiative Lifetime in Near-IR-Luminescent Ytterbium Cryptates: The Key

to Extremely High Quantum Yields

C. Doffek, M. Seitz, Angew. Chem. Int. Ed. 2015, 54, 9719-9721.

DOI: http://dx.doi.org/10.1002/anie.201502475

 

35) Breakdown of the Energy Gap Law in Molecular Lanthanoid Luminescence: The Smallest Energy Gap Is Not

Universally Relevant for Nonradiative Deactivation

C. Doffek, J. Wahsner, E. Kreidt, M. Seitz, Inorg. Chem. 2014, 53, 3263-3265.

DOI: http://dx.doi.org/10.1021/ic500017a


34) Perdeuterated 2,2'-Bipyridine-6,6'-Dicarboxylate - An Extremely Efficient Sensitizer for

Thulium Luminescence in Solution.

J. Wahsner, M. Seitz, Inorg. Chem. 2013, 52, 13301-13303.

DOI: http://dx.doi.org/10.1021/ic402652t

 

33) The First Enantiopure Lanthanoid Cryptate.

T. Güden-Silber, C. Doffek, C. Platas-Iglesias, M. Seitz, Dalton Trans. 2014, 43, 4238-4241.

(Invited contribution for the themed issue "New Talent: Europe").

DOI: http://dx.doi.org/10.1039/C3DT51289D

 

32) 4,4'-Bis(trifluoromethyl)-2,2'-Bipyridine - A Multipurpose Ligand Scaffold for Lanthanoid-Based

Luminescence / 19F NMR Probes.

T. Güden-Silber, K. Klein, M. Seitz,  Dalton Trans. 2013, 42, 13882-13888.

DOI: http://dx.doi.org/10.1039/C3DT50842K

 

31) From Solvated Ions to Ion-Pairing: A THz Study of Lanthanum(III) Hydration.

V. Sharma, F. Böhm, M. Seitz, G. Schwaab, M. Havenith, Phys. Chem. Chem. Phys. 2013, 15, 8383-8391.

DOI: http://dx.doi.org/10.1039/C3CP50865J

 

30) Understanding the Quenching Effects of Aromatic C-H- and C-D-Oscillators in Near-IR

Lanthanoid Luminescence.

C. Doffek, N. Alzakhem, C. Bischof, J. Wahsner, T. Güden-Silber, J. Lügger, C. Platas-Iglesias, M. Seitz, J. Am. Chem. Soc. 2012, 134, 16413-16423.

DOI: http://dx.doi.org/10.1021/ja307339f


29) Anomalous Reversal of C-H and C-D Quenching Efficiencies in Luminescent

Praseodymium Cryptates.

J. Scholten, G.A. Rosser, J. Wahsner, N. Alzakhem, C. Bischof, F. Stog, A. Beeby, M. Seitz, J. Am. Chem. Soc. 2012, 134, 13915-13917.

DOI: http://dx.doi.org/10.1021/ja306052u


28) Dependence of the Photophysical Properties on the Number of 2,2'-Bipyridine Units in a Series

of Luminescent Europium and Terbium Cryptates.

N. Alzakhem, C. Bischof, M. Seitz, Inorg. Chem. 2012, 51, 9343-9349.

DOI: http://dx.doi.org/10.1021/ic3010568


27) Rigid, Perdeuterated Lanthanoid Cryptates - Extraordinarily Bright Near-IR Luminophores.

C. Doffek, N. Alzakhem, M. Molon, M. Seitz, Inorg. Chem. 2012, 51, 4539-4545.

DOI: http://dx.doi.org/10.1021/ic202376k


26) Synthesis, Characterisation and Bioimaging of a Fluorescent Rhenium-Containing PNA Bioconjugates.

G. Gasser, A. Pinto, S. Neumann, A.M. Sosniak, M. Seitz, K. Merz, R. Heumann, N. Metzler-Nolte, Dalton Trans. 2012,

41, 2304-2313.

DOI: http://dx.doi.org/10.1039/c2dt12114j


25) Preparation and Biological Evaluation of Di-Hetero Organometallic-Containing PNA Bioconjugates.

G. Gasser, S. Neumann, I. Ott, M. Seitz, R. Heumann, N. Metzler-Nolte Eur. J. Inorg. Chem 2011, 5471-5478.

DOI: http://dx.doi.org/10.1002/ejic.201100734


24) Quantification of C-H Quenching in Near-IR Luminescent Ytterbium and Neodymium Cryptates.

C. Bischof, J. Wahsner, J. Scholten, S. Trosien, M. Seitz, J. Am. Chem. Soc. 2010, 132, 14334-14335.

DOI: http://dx.doi.org/10.1021/ja105768w


23) 3,2-HOPO Complexes of Near Infra-Red (NIR) Emitting Lanthanides: Efficient Sensitization

of Yb(III) and Nd(III) in Aqueous Solution.

E.G. Moore, J. Xu, S.C. Dodani, C.J. Jocher, A. D'Aleo, M. Seitz, K.N. Raymond, Inorg. Chem. 2010, 49, 4156-4166.

DOI: http://dx.doi.org/10.1021/ic902219t


22) Computational Estimation of Lanthanoid-Water Bond Lengths by Semiempirical Methods.

M. Seitz, N. Alzakhem, J. Chem. Inf. Model. 2010, 50, 217-220.

DOI: http://dx.doi.org/10.1021/ci9003442


21) Circularly Polarized Luminescence in Enantiopure Europium and Terbium Complexes with

Modular, All-Oxygen Donor Ligands.

M. Seitz, K. Do, A.J. Ingram, E.G. Moore, G. Muller, K.N. Raymond, Inorg. Chem. 2009, 48, 8469-8479.

DOI: http://dx.doi.org/10.1021/ic901079s


20) Highly Fluorescent Group 13 Metal Complexes With Cyclic, Aromatic Hydroxamic Acid Ligands.

M. Seitz, E.G. Moore, K.N. Raymond, Inorg. Chem. 2008, 47, 8665.

DOI: http://dx.doi.org/10.1021/ic800269w


19) Use of YbIII-Centered Near-Infrared (NIR) Luminescence To Determine the Hydration State of a

3,2-HOPO-Based MRI Contrast Agent.

E.G. Moore, M. Seitz, K.N. Raymond, Inorg. Chem. 2008, 47, 8571.

DOI: http://dx.doi.org/10.1021/ic801060x


18) Efficient route to highly water-soluble aromatic cyclic hydroxamic acid ligands.

M. Seitz, K.N. Raymond, Eur. J. Org. Chem. 2008, 2697.

DOI: http://dx.doi.org/10.1002/ejoc.200800147


17) Enantiopure, Octadentate Ligands as Sensitizers for Europium and Terbium Circularly Polarized

Luminescence in Aqueous Solution.

M. Seitz, E.G. Moore, A.J. Ingram, G. Muller, K.N. Raymond, J. Am. Chem. Soc. 2007, 129, 15468.

DOI: http://dx.doi.org/10.1021/ja076005e


16) The Lanthanide Contraction Revisited.

M. Seitz, A.G. Oliver, K.N. Raymond, J. Am. Chem. Soc. 2007, 129, 11153.

DOI: http://dx.doi.org/10.1021/ja072750f


15) 1,2-HOIQO - A Highly Versatile 1,2-HOPO Analogue.

M. Seitz, M.D. Pluth, K.N. Raymond, Inorg. Chem. 2007, 46, 351.

DOI: http://dx.doi.org/10.1021/ic0614869


14) Bis(pentamethylcyclopentadienyl)[(trimethylsilyl)methyl]scandium(III).

S.G. Minasian, J.D. Rinehart, P. Bazinet, M. Seitz, Acta Crystallogr., Sect. E: Struct. Rep. Online 2006, 62, m1823.

DOI: http://dx.doi.org/10.1107/S1600536806026602


13) Modular synthesis of chiral pentadentate bis(oxazoline) ligands.

M. Seitz, A. Kaiser, A. Tereshchenko, C. Geiger, Y. Uematsu, O. Reiser, Tetrahedron 2006, 62, 9973.

DOI: http://dx.doi.org/10.1016/j.tet.2006.08.003


12) (L)-[(R,R)-2,6-Bis(2-phenyl-4,5-dihydrooxazol-4-ylmethoxymethyl)pyridine]zinc(II) bis(trifluoromethane-

sulfonate) dichloromethane solvate.

M. Seitz, M. Zabel, O. Reiser, Acta Crystallogr., Sect. E: Struct. Rep. Online 2006, 62, m1517.

DOI: http://dx.doi.org/10.1107/S1600536806021210


11) Synthetic approaches towards structurally diverse g-butyrolactone natural-product-like compounds.

M. Seitz, O. Reiser, Curr. Opin. Chem. Biol. 2005, 9, 285.

DOI: http://dx.doi.org/10.1016/j.cbpa.2005.03.005


10) Enantiomerically Pure Pentagonal-Bipyramidal Metal Complexes with Predetermined Helicity in the

Solid and Solution States.

M. Seitz, A. Kaiser, S. Stempfhuber, M. Zabel, O. Reiser, Inorg. Chem. 2005, 44, 4630.

DOI: http://dx.doi.org/10.1021/ic050014b


9) Helical chirality in pentacoordinate zinc complexes - Selective access to both pseudoenantiomers with

one ligand configuration.

M. Seitz, S. Stempfhuber, M. Zabel, M. Schütz, O. Reiser, Angew. Chem. Int. Ed. 2005, 44, 242.

DOI: http://dx.doi.org/10.1002/anie.200460843


8) Predetermined helical chirality in octahedral complexes with a novel pentadentate C2-symmetrical

chiral bis(oxazoline) ligand.

M. Seitz, A. Kaiser, D.R. Powell, A.S. Borovik, O. Reiser, Adv. Synth. Catal. 2004, 346, 737.

DOI: http://dx.doi.org/10.1002/adsc.200404020


7) Helical, Nonracemic Inorganic-Organic Hybrid Polymers of Cadmium Halides with Pentadentate

Bis(oxazoline) Ligands.

M. Seitz, A. Kaiser, S. Stempfhuber, M. Zabel, O. Reiser, J. Am. Chem. Soc. 2004, 126, 11426.

DOI: http://dx.doi.org/10.1021/ja0469784


6) New bis(oxazoline) ligands with secondary binding sites for the asymmetric cyclopropanation of furans.

M. Schinnerl, C. Böhm, M. Seitz, O. Reiser, Tetrahedron: Asymmetry 2003, 14, 765.

DOI: http://dx.doi.org/10.1016/S0957-4166(03)00094-6


5) Enantioselective synthesis of paraconic acids.

R. B. Chhor, B. Nosse, S. Sörgel, C. Böhm, M. Seitz, O. Reiser, Chem. Eur. J. 2003, 9, 260.

DOI: http://dx.doi.org/10.1002/chem.200390019


4) New Applications of Bis(oxazoline) Ligands in Catalysis: Asymmetric 1,2- and 1,4-Addition of ZnR2 to Carbonyl

Compounds.

M. Schinnerl, M. Seitz, A. Kaiser, O. Reiser, Org. Lett. 2001, 3, 4259.

DOI: http://dx.doi.org/10.1021/ol016925g


Patents / Book Chapters / Book Reviews

 

3) Pentacoordinating bis(oxazoline) ligands with secondary binding sites (in: Activating Unreactive Substrates:

The Role of Secondary Interactions; Eds.: C. Bolm, F.E. Hahn)

C.A. Schall, M. Seitz, A. Kaiser, O. Reiser, Wiley-VCH, Weinheim 2009.

ISBN: 9783527318230.


2) Preparation of 2-hydroxy-1-oxo-1,2-dihydroisoquinoline chelating agents and their lanthanide complexes with

diagnostic and pharmaceutical applications.

M. Seitz, K.N. Raymond, Patent WO2007/121453 (2007).


1) Principles and Applications of Asymmetric Synthesis (Book Review).

M. Seitz, Angew. Chem. Int. Ed. 2001, 40, 3922.

DOI: http://dx.doi.org/10.1002/1521-3773(20011015)40:20%3C3922::AID-ANIE3922%3E3.0.CO;2-P